Sunna 1

On wakening up from sleep 

Sunna: Rub the face and the eyes with both hands to remove the haze of sleep.(Shamail e Tirmizi) 

Sunna: Recite الحمد لله الذي أحيانا بعدما أماتنا وإليه النشور(Shamail e Tirmizi) 

Sunna: Clean the mouth using miswak. (Abu Dawud)

This is a Sunna separate from using miswak in wudu.